The kinetics of the oxidation of dimethylsulfoxide by Cerium(IV) in perchloric acid has been investigated spectrophotometrically. The water role has been elucidates by using acidity criteria. A tentative mechanism consistent with the kinetics is dis- ## Kinetische Untersuchung der Oxidation von Dim
Kinetic identification of the reactive cerium(IV) species in the oxidation of methyliminodiacetic acid (MIDA) in acidic sulfate media
โ Scribed by S.B. Hanna; R.K. Hessley; L.M. Nicholson
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 142 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0020-1693
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The kinetics of the cerium(1V) oxidation of p-nitro and p-methoxymandelic acids have been investigated in H2S04-MHS04 (M+ = Li+ , Na+, K+) and H2S04-MC104 (M+ = H+, Na+) mixtures a t a constant total electrolyte concentration of 2.00 mol/dm3. The oxidation of p-nitromandelic acid proceeds through tw
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## Abstract The Ce(IV) oxidation of the fiveโ, sixโ, and sevenโmembered ring ฮฑโhydroxycycloalkanecarboxylic (C5, C6, and C7) acids to the corresponding cyclic ketones has been studied in acidic perchlorate media. The data may be interpreted in terms of a mechanism which involves fast preequilibrium