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Kinetic hydrogen isotope effects in the piperidino dehalogenation of heteroaromatic substrates

✍ Scribed by Italo Giardi; Gabriello Illuminati; Giancarlo Sleiter


Book ID
104215385
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
234 KB
Volume
9
Category
Article
ISSN
0040-4039

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Lack of kinetic hydrogen isotope effect
✍ R. P. DurΓ‘n; V. T. Amorebieta; A. J. Colussi πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 636 KB

Second order rate constants for C2H2 or C2D2 polymerizations into vinylacetylene and higher C,H, products have been measured in a static reactor by dynamic mass spectrometry between"770-980 K. They are nearly identical within experimental error (-+50%). It is shown that these results are consistent