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Kinetic evidence of anionic intermediates in the base-catalyzed cleavage of glycosidic bonds in the methyl D-glucopyranosides

✍ Scribed by Y.Z. Lai

Book ID
108308104
Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
619 KB
Volume
24
Category
Article
ISSN
0008-6215

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πŸ“œ SIMILAR VOLUMES

Kinetic evidence for the occurrence of k
Kinetic evidence for the occurrence of kinetically detectable intermediates in the cleavage of N-ethoxycarbonylphthalimide under N-methylhydroxylamine buffers
✍ M. Niyaz Khan πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 172 KB

## Abstract The kinetics of the aqueous cleavage of __N__‐ethoxycarbonylphthalimide (NCPH) in CH~3~NHOH buffers of different pH reveals that the cleavage follows the general irreversible consecutive reaction path NCPH $\buildrel{k\_{1\,{\rm obs}}}\over\longrightarrow$ ENMBC $\buildrel{k\_{2\,{\rm