Kinetic evidence for the formation of the carbene anion radical (EtO2C)2C-.cntdot.
โ Scribed by Van Galen, Dean A.; Young, Mark P.; Hawley, M. Dale; McDonald, Richard N.
- Book ID
- 126931622
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 808 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The initial rates of formation of the major products in the thermal reactions of ethylene at temperatures in the neighborhood of 800 K have been measured in the presence and absence of the additives neopentane and ethane. It has been shown that in the absence of the additive the main initiation proc
The kinetics of the gas-phase dehydrogenation of cyclopentane to cyclopentene is found to be consistent with a slow attack by a n I atom (step 4, text) on cyclopentane in the range 282-382OC. The measured rate constants fit the Xrrhenius equation, log k, = 11.95 f 0.08 -(24.9 f 0.23)/0 1 mole-l sec-