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Kinetic Evidence for Five-Coordination in AlOH(aq)2+ Ion

✍ Scribed by Swaddle, T. W.


Book ID
119970245
Publisher
American Association for the Advancement of Science
Year
2005
Tongue
English
Weight
236 KB
Volume
308
Category
Article
ISSN
0036-8075

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Kinetic evidence for the occurrence of t
✍ M. Niyaz Khan; M. S. O. O πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 574 KB

The kinetics of hydrolytic cleavage of saccharin has been studied at 60Β°C within the [GH] range of 0.1 to 3.0 M. The observed pseudo first-order rate constants, kobs, follow an empirical relationship: k,,, = B[6H] + [C[aH]'. TheB and C terms are attributed to the formation of dianionic and trianioni