Kinetic energy release and ion structure: [C6H6O]+˙
✍ Scribed by A. Maquestiau; R. Flammang; G. L. Glish; J. A. Laramée; R. G. Cooks
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 283 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1076-5174
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## Abstract Collisionally activated spectra demonstrate that CH~3~CH~2~CO^+^ rather than \documentclass{article}\pagestyle{empty}\begin{document}${\rm CH}\_{\rm 2} = {\rm CHCH = }\mathop {\rm O}\limits^{\rm + } {\rm H}$\end{document} is formed in the metastable losses of hydrogen from [C~3~H~6~O]^
Appearance energy and kinetic energy release measurements together with isotopic labelling have shown that the metastable molecular ion of 1-phenylpmpenol isomerizes into those of cinnamic alcohol and 3-phenylpropanal prior to loss of ketene. =C! labelling and thennodynamic considerations prove that