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Kinetic differences between the incorporation of zinc(II) and cadmium(II) into porphyrins and N-methylporphyrins

✍ Scribed by Hambright, P.; Shah, B.; Shears, B.


Book ID
127069564
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
421 KB
Volume
10
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of zinc(II), cadm
✍ Wen Juan Ruan; Zhi Ang Zhu; Hong Wei Chen; Zhi Hui Zhang; Yun Ti Chen πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 148 KB πŸ‘ 2 views

The kinetics of Zn(II), Cd(II), and Hg(II) incorporation into meso tetrameta-tolueneporphyrin (H 2 T(m-CH 3 )PP) in acetone have been studied by means of stopped-flow method. A unified reaction mechanism was proposed and the kinetic parameters were obtained by nonlinear least-square methods. The eff