✦ LIBER ✦

Kinetic deuterium isotope effects in the reaction of Vaska's compound (Ph3P)2Ir(CO)Cl with methyl iodide and MeOSO2CF3

✍ Scribed by Stang, Peter J.; Schiavelli, Melvyn D.; Chenault, H. Keith; Breidegam, Julie L.

Book ID: 126227756
Publisher: American Chemical Society
Year: 1984
Tongue: English
Weight: 276 KB
Volume: 3
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00085a036

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Interpretation of the Gas-Phase Solvent

Interpretation of the Gas-Phase Solvent Deuterium Kinetic Isotope Effects in the S N 2 Reaction Mechanism: Comparison of Theoretical and Experimental Results in the Reaction of Microsolvated Fluoride Ions with Methyl Halides

✍ Davico, Gustavo E. 📂 Article 📅 2006 🏛 American Chemical Society 🌐 English ⚖ 125 KB

β-deuterium kinetic isotope effects in t

β-deuterium kinetic isotope effects in the solvolysis of 2-aryl-1,1,1-trifluoro-2-propyl tosylates and of 2-aryl-2-profyl p-nitrobenzoates. Evidence for a variation of the contribution of α-methyl substituent in stabilizing cationic reaction centers with different electron demand

✍ Kwang-Ting Liu; Yuh Wern Wu 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 251 KB

A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue