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Kinetic control of stereochemistry in the addition of unsymmetrical ketens to cyclopentadiene

✍ Scribed by Brook, P. R.; Harrison, J. M.; Duke, A. J.

Book ID
115457556
Publisher
Royal Society of Chemistry
Year
1970
Weight
232 KB
Volume
10
Category
Article
ISSN
0577-6171

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## Abstract The title reactions have been investigated in a static system. The addition of acetylene to cyclopentadiene (CPD) results in formation of norbornadiene (BCH), cycloheptatriene (CHT), and toluene (T), while BCH decomposition produces CPD, C~2~H~2~, CHT, and T. Kinetic studies, comprising