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Kinetic constants for the inhibition of camel retinal acetylcholinesterase by the carbamate insecticide lannate

✍ Scribed by Mohammad A. Kamal; Abdulaziz A. Al-Jafari


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
141 KB
Volume
13
Category
Article
ISSN
1095-6670

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✦ Synopsis


We have designed this study to determine various kinetic parameters of camel retinal membranebound acetylcholinesterase (AChE; EC 3.1.1.7) inhibition by carbamate insecticide lannate [methyl N-{{(methylamino)carbonyl}oxy} ethanimidothioate]. All these kinetic constants were derived by simple graphical methods. The value of kinetic parameters was estimated as follows: 0.061 ( lM) ‫1‬ , 1.14 ( lM) ‫1‬ , 0.216 lM, 0.016 min ‫1‬ , 0.0741 ( lM min) ‫1‬ , 0.746 lM, and 4.42 lM for velocity constant (K v ), new inhibition constant (K nic ), dissociation constant (K d ), carbamylation rate constant (k 2c ), overall carbamylation rate constant ( ),

k 2 50% inhibition constant (K I50 ), and 99% inhibition constant (K I99 ), respectively. These unique methods may be used to estimate such kinetic parameters for time-dependent inhibition of enzymes by variety of chemicals, insecticides, herbicides, and drugs.