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Kinetic compensation effect as a mathematical consequence of the exponential rate constant

✍ Scribed by Nobuyoshi Koga; Jaroslav Šesták

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
560 KB
Volume
182
Category
Article
ISSN
0040-6031

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The kinetics of polyesterification. III.
The kinetics of polyesterification. III. A mathematical model for quantitative prediction of the apparent rate constants
✍ Chen Chong Lin; Ping Chang Yu 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 302 KB

A mathematical model for the apparent constants k l and k z which presents a quantitative explanation of the observed kinetic behavior in both uncatalyzed and acid-catalyzed polyesterification between ethylene glycol and a dibasic acid in different initial molar ratios was developed. This model cons