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Kinetic aspects of highly exothermic electron-transfer reactions in heterogeneous systems

✍ Scribed by Nakabayashi, Seiichiro; Fujishima, Akira; Honda, Kenichi


Book ID
118139438
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
668 KB
Volume
87
Category
Article
ISSN
0022-3654

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On the frequency factor in electron tran
✍ R. A. Marcus πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 437 KB

## Abstract Consideration of current information on the dependence of the electron transfer rate on the radial separation distance and on the reactantsβ€² radial distribution function suggests for adiabatic transfers a frequency factor closer to 10^12^__M__^βˆ’1^ s^βˆ’1^ than to 10^11^__M__^βˆ’1^ s^βˆ’1^. On