𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetic and thermodynamic study of thiolato and sulfenato Co(III) complexes in water–acetonitrile mixtures

✍ Scribed by Monika Aranyosiová; Ján Benko; Ol'Ga Vollárová

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
102 KB
Volume
36
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Rate constants are reported for peroxodisulfate as well as periodate oxidation of [Co(en) 2 {SCH 2 CH(COO)NH 2 }] + , [Co(en) 2 (SCH 2 CH 2 NH 2 )] 2+ , and [Co(en) 2 (SOCH 2 CH 2 NH 2 )] 2+ in water-acetonitrile mixtures. The dependence of rate constants on the acetonitrile concentration is established and discussed. Ancillary information relevant to solvation of reactants has been obtained from solvatochromism and from Gibbs transfer functions. The solvent effect is discussed from the viewpoint of change in solvation of initial and transition state on going from water to water-acetonitrile mixtures.

📜 SIMILAR VOLUMES

Kinetic studies on N-Mannich bases of 3-
Kinetic studies on N-Mannich bases of 3-hydrazonoindolin-2-one in water–ethanol and water–acetonitrile mixtures
✍ Amel M. Ismail 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 110 KB

## Abstract Various isatin–N‐Mannich bases have shown antiviral and tuberculosatic activity. A reaction of 3‐hydrazonoindolin‐2‐one was performed efficiently with morpholine in the presence of formaldehyde. Kinetic studies have revealed no reaction between 3‐hydrazonoindolin‐2‐one and morpholine in

Kinetics of formation, dissociation, and
Kinetics of formation, dissociation, and redox reactions of the benzyl radical-Cu(II) ion complex in a 10% acetonitrile-90% water mixture
✍ Ahmed Mayouf; Helge Lemmetyinen; Irina Sychttchikova; Jouko Koskikallio 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 350 KB

The rate constant of formation, dissociation, and redox reaction of the benzyl radicalcopper(I1) ion complex have been determined at temperatures from 274 K to 333 K by laser flash photolysis of 1,3-diphenyl-2-propanone (DBK) in a 10% acetonitrile-90% water mixture containing copper(I1)perchlorate.

Kinetics of aquation of Co(III) complex
Kinetics of aquation of Co(III) complex in binary aqueous mixtures and effect of multiparameters of the solvent on the reaction rate
✍ Gehan M. El-Subruiti; Magda F. Fathalla; Yasser R. El-Marassi 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB 👁 1 views

## Abstract Kinetics and solvent effects of the aquation of trans[Co(4‐(Etpy)~4~Cl~2~]^+^ have been studied in ethanol + water ranging from 0 to 60% (v/v) and urea + water of various solvent compositions up to 40% (w/w) of organic solvent. Thermodynamic activation parameters were computed and discu