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Kinetic and thermodynamic character of reducing species produced on pulse radiolysis of acetonitrile

✍ Scribed by Bell, Ian P.; Rodgers, Michael A. J.; Burrows, Hugh D.


Book ID
118135837
Publisher
The Royal Society of Chemistry
Year
1977
Weight
870 KB
Volume
73
Category
Article
ISSN
0300-9589

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The transient absorption bands dm 3 9 Οͺ1 ( Ο­ 330, 525 nm, k Ο­ 5 Ο« 10 mol max f obtained on pulse radiolysis of N 2 O-saturated neutral aqueous solution of 4,4Ј-thiodi-Οͺ1 s ) phenol (TDPH) are due to the reaction of TDPH with ΠΈOH radicals and are assigned to phenoxyl radical formed on fast deprotonat