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Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 9. A sterically hindered cationic hydride, [H4Re(PMe2Ph)4]+

✍ Scribed by Kristjansdottir, S. Soley.; Loendorf, Amy J.; Norton, Jack R.

Book ID: 126035401
Publisher: American Chemical Society
Year: 1991
Tongue: English
Weight: 298 KB
Volume: 30
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00023a037

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Kinetic and thermodynamic acidity of hyd

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Chemistry of di- and tri-metal complexes

Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 9. Reactivity of the cations [MPt(�-CC6H4Me-4)(CO)2(PR3)2(?-C5H5)]+(M = Mn or Re, Pr3= PMe3 or PMe2Ph) towards tertiary phosphines and the toluene-p-thiolate anion; X-ray crystal structures of [MnPt{�-C(PMe3)C6H4Me-4}(CO)2(PMe3)2(?-C5H5)][BF4] and [MnPt(SC6H4Me-4){�-C(PMe3)C6H4Me-4}(�-CO)(CO)(PMe3)(?-C5H5)]

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