✦ LIBER ✦

Kinetic and mechanistic study of the mercury(II)-catalyzed substitution of cyanide in hexacyanoruthenate(II) by pyrazine

✍ Scribed by Radhey M. Naik; Amit K. Verma; Abhinav Agarwal; Abhas Asthana

Publisher: Springer
Year: 2009
Tongue: English
Weight: 363 KB
Volume: 34
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-008-9180-x

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics of the mercury(II)-catalyzed su

Kinetics of the mercury(II)-catalyzed substitution of coordinated cyanide ion in hexacyanoruthenate(II) by nitroso-R-salt

✍ Radhey M. Naik; Abhinav Agarwal; Amit K. Verma; Shiv Bali S. Yadav; Basant Kumar 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 298 KB

## Abstract The kinetics and mechanism of Hg^2+^‐catalyzed substitution of cyanide ion in an octahedral hexacyanoruthenate(II) complex by nitroso‐R‐salt have been studied spectrophotometrically at 525 nm (__λ__~max~ of the purple‐red–colored complex). The reaction conditions were: temperature = 45.

The formation of an antitubercular compl

The formation of an antitubercular complex [Fe(CN)5(INH)]3− through mercury(II)-catalyzed ligand substitution reaction: A kinetic and mechanistic study

✍ Radhey M. Naik; Surendra Prasad; Shiv B. S. Yadav; R. Rastogi; R. K. Tiwari 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 375 KB 👁 1 views

## Abstract The kinetics and mechanism of the formation of an antitubercular complex [Fe(CN)~5~(INH)]^3−^ based on the substitution reaction between K~4~[Fe(CN)~6~] and isoniazid (INH), i.e., isonicotinohydrazide, catalyzed by Hg^2+^ in aqueous medium was studied spectrophotometrically at 435 nm (t

A study of mercury(II)-catalysed substit

A study of mercury(II)-catalysed substitution of cyanide in hexacyanoferrate(II) by 2-methylpyrazine: effects of inhibitor on the catalysed reaction

✍ Neetu Bansal 📂 Article 📅 2009 🏛 Springer 🌐 English ⚖ 548 KB

Kinetics and mechanism of ligand exchang

Kinetics and mechanism of ligand exchange of coordinated cyanide in hexacyanoferrate(II) by nitroso-R-salt in the presence of mercury(II) as a catalyst

✍ R. M. Naik; Joy Sarkar; D. D. Chaturvedi 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB

## Abstract The kinetics of Hg(II)‐catalyzed reaction between hexacyanoferrate(II) and nitroso‐R‐salt has been followed spectrophotometrically by monitoring the increase in absorbance at 720 nm, the λ~max~ of green complex, [Fe(CN)~5~ N‐R‐salt]^3−^ as a function of pH, ionic strength, temperature,

An independent kinetic and mechanistic s

An independent kinetic and mechanistic study of the secondary reactions in the substitution of [FeL(OH)](n−2)−(L= triethylenetetraaminehexaacetic acid) by cyanide ions

✍ Surendra Prasad; Prem C. Nigam; Radhey M. Naik 📂 Article 📅 1990 🏛 Springer 🌐 English ⚖ 470 KB

A Kinetic and Mechanistic Study on Subst

A Kinetic and Mechanistic Study on Substitution of Aqua Ligands fromcis-diaqua-bis-(bipyridyl)-ruthenium(II) Complex by Thiosemicarbazide in Aqueous Medium

✍ Aishwarya Mukherjee (Goswami); De Krishna 📂 Article 📅 2005 🏛 Springer 🌐 English ⚖ 342 KB