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Kinetic and mechanistic studies of the tandem enediyne-radical cyclization

โœ Scribed by Grissom, Janet Wisniewski; Calkins, Trevor L.

Book ID
126768908
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
756 KB
Volume
58
Category
Article
ISSN
0022-3263

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Mechanistic studies on the novel 7-endo selective radical cyclization were carried out. The reaction afforded three products, 7-endo product, 6-exo product, and reduced product. The distribution of these products was estimated by GC analyses. The 7-endo/6-exo selectivity was almost constant against