Kinetic and mechanistic studies of the N-bromosuccinimide-promoted oxidative decarboxylation of glycine, DL-alanine, and DL-valine
✍ Scribed by Gopalakrishnan, Ganesa; Hogg, John L.
- Book ID
- 118029424
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 885 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The kinetics of oxidation of [Cr^III^(Dpc)(Asp)(H~2~O)~2~] (Dpc = dipicolinic acid and Asp = DL‐aspartic acid) by __N__‐bromosuccinimide (NBS) in aqueous solution have been found to obey the equation: equation image where __k__~2~ is the rate constant for the electron transfer process
## Abstract Dipeptides (DP), namely valyl–glycine (Val–Gly), alanyl–proline (Ala–Pro), and valyl–proline (Val–Pro) were synthesized by classical solution phase methods and characterized. The kinetics of oxidation of amino acids (AA) and DP by __N__‐bromosuccinimide (NBS) was studied in the presence