✦ LIBER ✦

Kinetic and mechanistic studies of blue tetrazolium reaction with phenylhydrazines

✍ Scribed by Edward R. Biehl; Robert Wooten; C. T. Kenner; Robert E. Graham

Publisher: John Wiley and Sons
Year: 1978
Tongue: English
Weight: 460 KB
Volume: 67
Category: Article
ISSN: 0022-3549
DOI: 10.1002/jps.2600670714

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction kinetics of blue tetrazolium with selected arylhydrazines were investigated under pseudo-first-order conditions. The reaction rate constants were obtained at various temperatures, and the enthalpy (8.4-11.2 kcal/mole) and entropy (-38--45 eu) of activations were calculated. A Hammett plot yielded a straight line with a slope of 0.52. The reaction was inhibited by atmospheric oxygen and iodine. A free radical mechanism is presented.

📜 SIMILAR VOLUMES

Kinetics and mechanism of blue tetrazoli

Kinetics and mechanism of blue tetrazolium reaction with corticosteroids

✍ Raul M. Oteiza; Robert S. Wooten; Charles T. Kenner; Robert E. Graham; Edward R. 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 439 KB

Kinetic study of USP blue tetrazolium as

Kinetic study of USP blue tetrazolium assay with methylprednisolone, hydrocortisone, and their hemisuccinate esters by high-pressure liquid chromatography

✍ Marilyn Dix Smith 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 493 KB

Kinetic and Mechanistic Studies of Carbo

Kinetic and Mechanistic Studies of Carboxylic Acid–Bisoxazoline Chain-Coupling Reactions

✍ Laurent Néry; Hervé Lefebvre; Alain Fradet 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 164 KB

## Abstract Kinetic studies of the reactions between a model carboxylic acid and bisoxazoline coupling agents, namely 2,2′‐(1,3‐phenylene)bis(2‐oxazoline) (**mbox**), 2,2′‐(1,4‐phenylene)bis(2‐oxazoline) (**pbox**), and 2,2′‐(2,6‐pyridylene)bis(2‐oxazoline) (**pybox**), were carried out in bulk at

Gas-phase reaction of NO3 radicals with

Gas-phase reaction of NO3 radicals with isoprene: a kinetic and mechanistic study

✍ Torsten Berndt; Olaf Böge 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 233 KB 👁 2 views

The gas-phase reaction of NO 3 radicals with isoprene was investigated under flow conditions at 298 K in the pressure range 6.8 Ͻ P(mbar) Ͻ 100 using GC-MS/FID, direct MS, and long-path FT-IR spectroscopy as detection techniques. By means of a relative rate method, the rate constant for the primary

Kinetic studies of hydralazine reaction

Kinetic studies of hydralazine reaction with acetaldehyde

✍ John P. O'Donnell; Woodrow J. Proveaux; Joseph K. H. Ma 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 310 KB 👁 1 views

Kinetic and mechanistic study of the rea

Kinetic and mechanistic study of the reaction of O(1D) with CF2HBr

✍ R. S. Strekowski; J. M. Nicovich; P. H. Wine 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB

A laser flash photolysis-resonance fluorescence technique has been employed to investigate the kinetics and mechanism of the reaction of electronically excited oxygen atoms, O( 1 D), with CF 2 HBr. Absolute rate coefficients (k 1 ) for the deactivation of O( 1 D) by CF 2 HBr have been measured as a