The effect of fullerene (C 60 ) on the radical polymerization of methyl methacrylate (MMA) in benzene was studied kinetically and by means of ESR, where dimethyl 2,2Π-azobis(isobutyrate) (MAIB) was used as initiator. The polymerization rate (R p ) and the molecular weight of resulting poly(MMA) decr
Kinetic and ESR studies on radical polymerization behavior of N-(2-phenylethoxycarbonyl)methacrylamide
β Scribed by Makiko Seno; Tomoya Fukui; Tomohiro Hirano; Tsuneyuki Sato
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 175 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
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π SIMILAR VOLUMES
Polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) was kinetically investigated in ethanol using dimethyl 2,2Π-azobisisobutyrate (MAIB) as initiator. The overall activation energy of the homogeneous polymerization was calculated to be 71 kJ/mol. The polymerization rate (R p ) was expre
The copolymerization of p-tert-butoxystyrene ( TBOSt ) ( M 1 ) and di-n -butyl maleate ( DBM ) ( M 2 ) with dimethyl 2,2 -azobisisobutyrate ( MAIB ) in benzene at 60ΠC was studied kinetically and by means of ESR spectroscopy. The monomer reactivity ratios were determined to be r 1 Γ 2.3 and r 2 Γ 0