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Kinetic Analysis of the Thermal Isomerizations Linking 1-( E )-Propenyl-2-methylcyclobutanes with ( Z )- and ( E )-1,5-Octadiene and 3-Ethylhexa-1,5-diene

โœ Scribed by Baldwin, John E.; Burrell, Richard C.


Book ID
127140542
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
102 KB
Volume
107
Category
Article
ISSN
1089-5639

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The reaction of cationic diolefinic rhodium(I) complexes with 2-(diphenylphosphino)benzaldehyde (pCHO) was studied. [Rh(cod) 2 ]ClO 4 (cod cycloocta-1,5-diene) reacted with pCHO to undergo the oxidative addition of one pCHO with (1,2,3-h)cyclooct-2-en-1-yl (h 3 -C 8 H 13 ) formation, and the coordin