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Kinetic analysis of the sorption of copper(II) ions on chitosan

✍ Scribed by WH Cheung; JCY Ng; G Mckay

Publisher
Wiley (John Wiley & Sons)
Year
2003
Tongue
English
Weight
202 KB
Volume
78
Category
Article
ISSN
0268-2575

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✦ Synopsis

Abstract

The removal of copper ions from aqueous effluents by chitosan was studied in equilibrium and agitated batch contacting systems. The sorption capacities of chitosan for copper ions are 1.26 and 1.12 mmol g^βˆ’1^ at pH 3.5 and 4.5, respectively. The equilibrium experimental data were best correlated by the Langmuir equation. The kinetics of sorption were studied at an initial solution pH of 4.5 and a chitosan particle size of 355–500 Β΅m. The kinetics were analyzed using four models: the pseudo‐first‐order, pseudo‐second‐order, modified second‐order and Elovich equations. The rate parameters for the four models were determined and the Elovich equation provided the best correlation of the experimental kinetic data. Copyright Β© 2003 Society of Chemical Industry

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