Kinetic analysis of sodium nitrate(III) inversion with nitric acid(V)

✍ Scribed by Jerzy Piotrowski; Krzysztof Piotrowski

• Book ID: 104427274
• Publisher: Elsevier Science
• Year: 2003
• Tongue: English
• Weight: 101 KB
• Volume: 95
• Category: Article
• ISSN: 1385-8947
• DOI: 10.1016/s1385-8947(03)00113-x

✦ Synopsis

Kinetic measurements of the sodium nitrate(III) inversion with the nitric acid(V) process, carried out in the range of c 0NaNO 2 : 0.25-0.5 mol/dm 3 , c 0HNO 3 : 1.5-3.0 mol/dm 3 , T = 303-353 K, Re m = 8500, were presented. A reaction rate equation and Arrhenius equation parameters were determined on the basis of the results obtained. It was found that in the examined parameter ranges the overall process rate could be described by a second-order kinetic equation.