Kinematic perturbations on the benzene 1B2u ← 1A1g two-photon spectrum: s-C6H3D3
✍ Scribed by Richard P. Rava; Lionel Goodman
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 248 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The importance of kinematic perturbations on the two-photon spectrum of benzene corresponding to the 'Bz, 6 'A,, transition is demonstrated by the spectrum of s-benzene-d3 iy in S-C6H3D3-pg, absent in the C&e spectrum (where it is ezg) appears strong-
📜 SIMILAR VOLUMES
We perform multiconfiguration quadratic response theory calculations of vibronically induced symmetry and parity forbidden 'A,k-'B2,, two-photon transitionsofbenzene. The followingorder ofvibronic activity is found; Y,.,> Y,~> Y,~z= Y,~> Y!,> Y,\*> Y?,,. The two-photon activity is crucially dependen
The two-photon absorption spectra at -1 cm-' resolution is presented for benzene46 and benzenedb. A number ofvibrations of bt,, bzu. etu and czu symmetry are assigned and the results compared with theoretical espectations. It appears as if the n-rlectron states dominate the coupling to the radiatio
The absorption spectra of biphenylJl lo and -dlo crystals in the region of the lAlg + lBag, lBzu transitions are interpreted in terms of vibronic coupling of the two closely spaced electronic states by six bl, vibrations.
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