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Ketone synthesis via palladium-catalyzed carbonylation of organoaluminium compounds

✍ Scribed by N.A. Bumagin; A.B. Ponomaryov; I.P. Beletskaya


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
194 KB
Volume
26
Category
Article
ISSN
0040-4039

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Cyclic ketones react with PdCl 2 in methanol under a CO atmosphere to give mainly diesters by a ring cleavage reaction along with some chloro-substituted monoester. 13 CO labeling experiments indicate the major product is formed by a mechanism involving Pd(II)-CO 2 CH 3 insertion across the double b