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Keto-enol tautomerism and nonlinear optical properties in β-diketones containing [2.2]paracyclophane

✍ Scribed by Sergeeva, Elena V.; Puntus, Lada N.; Kajzar, Francois; Rau, Ileana; Sahraoui, Bouchta; Pekareva, Irina S.; Suponitsky, Kyrill Yu.; Bushmarinov, Ivan S.; Lyssenko, Konstantin A.


Book ID
120578353
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
844 KB
Volume
36
Category
Article
ISSN
0925-3467

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Keto–enol tautomerism in β-ketoesters: C
✍ M. M. Schiavoni; H. E. Di Loreto; A. Hermann; H.-G. Mack; S. E. Ulic; C. O. Dell 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 187 KB

The tautomeric equilibria of the b-ketoesters [CH 3 C(O)CH 2 C(O)OCH 3 (I), CH 3 C(O)CHClC(O)OCH 3 (II), CH 3 C(O)CH 2 C(O)OCH 2 CH 3 (III) and CH 3 C(O)CHClC(O)OCH 2 CH 3 (IV)] were studied by NMR spectroscopy and, in the case of I and II, by quantum chemical calculations (ab initio and density fun