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Ketene. Part 21. Reactions of heterocumulenes with nitrones

✍ Scribed by Evans, Andrew R.; Hafiz, Mushtaq; Taylor, Giles A.


Book ID
118747409
Publisher
Royal Society of Chemistry
Year
1984
Weight
739 KB
Category
Article
ISSN
1472-7781

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Reaction of nitrones with silyl ketene a
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## Abstract Theoretical calculations at the DFT level indicate that the reaction of a nitrone with a silyl ketene acetal proceeds, contrary to previous suggestions, through a classical 1,3‐dipolar cycloaddition, followed by a silyl group transfer step to give the open‐chain product. Introduction of