K3Cr2(PS4)3: A New Chromium Thiophosphate with a One-Dimensional [Cr2(PS4)3]3- Anion Chain.
β Scribed by Volkmar Derstroff; Juergen Ensling; Vadim Ksenofontov; Philipp Guetlich; Wolfgang Tremel
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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hr Οͺ1 ), we obtained small dark entangled needles with me-The crystal structure of NaTi 2 P 3 S 12 was determined from tallic lustre. These air sensitive single crystals were kept single-crystal X-ray diffraction data. This compound was oband handled in a dry glove box. tained as dark needles by hea
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Two new alkali metal chromium thiophosphates, Na 3 Cr 2 P 3 S 12 and K 3 Cr 2 P 3 S 12 , have been synthesized and their structure determined from single-crystal or powder X-ray di4raction analyses. These isostructural compounds, which exhibit a novel structural arrangement, crystallize in the monoc