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K2−xTi2(PO4)3 with 0 ≤ x ≤ 0.5: A mixed-valence nonstoichiometric titanophosphate with the langbeinite structure

✍ Scribed by A. Leclaire; A. Benmoussa; M.M. Borel; A. Grandin; B. Raveau


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
417 KB
Volume
78
Category
Article
ISSN
0022-4596

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A new series of layered ferrites (Tl 1.5 Hg 0.5 )Sr 3؊x Ba x Fe 2 O 9؊ has been synthesized and characterized for the composition range 04x42. The structure has been refined from powder XRD data and shown to be similar to that of the tetragonal Tl-2212type superconducting copper oxides. Electron dif