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K1.10Zr2Se6, Rb0.86Zr2Se6 and Cs0.80Zr2Se6. The First Intercalation Compounds of Zirconium Triselenide.

✍ Scribed by Kurt O. Klepp; Norbert A. Harringer; Andreas Kolb


Publisher
John Wiley and Sons
Year
2003
Weight
66 KB
Volume
34
Category
Article
ISSN
0931-7597

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K 2 W 6 Br 14 (I), Rb 2 W 6 Br 14 (II), and Cs 2 W 6 Br 14 (III) were formed by reactions of W 6 Br 12 with the corresponding alkali metal bromides in evacuated silica tubes with a temperature gradient of 925 K/915 K. (I) crystallizes in the cubic space group Pn3 (no. 201), a = 13.808 A Ê , Z = 4, c