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Josiphos Ligands with an Imidazolium Tag and their Application for the Enantioselective Hydrogenation in Ionic Liquids

✍ Scribed by Xiangdong Feng; Benoît Pugin; Ernst Küsters; Gottfried Sedelmeier; Hans-Ulrich Blaser


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
93 KB
Volume
349
Category
Article
ISSN
1615-4150

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✦ Synopsis


Abstract

Josiphos ligands bearing an imidazolium moiety show high efficiency and reusability for the rhodium‐catalyzed enantioselective hydrogenation of methyl acetamidoacrylate (MAA) and dimethyl itaconate (DMI) in biphasic co‐solvent/ionic liquid combinations.


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