✦ LIBER ✦

Jahn—teller distortions in copper(II) complexes as determined from ESR powder spectra

✍ Scribed by B. Nieuwenhuijse; J. Reedijk

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 244 KB
Volume: 22
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)80570-6

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✦ Synopsis

Cations Cu(lipand)6 2+doped in lattices of non.cubic Zn(ligand)6(anion)z xc shown try have ESR powder spectra. corresponding with two types of cations, distorted octAedr;ll and regulu octahedral. Upon lowcring of the tcmpcracure the number of distorted molecules increases. Despite of rhe non-cubic symmetry the results xre csscncislly simi-I;u to single cryst;ll observations nnd investigations on cubic lattices.