Iterative codes for fitting complete spectra
✍ Scribed by R.L. Coldwell
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 381 KB
- Volume
- 242
- Category
- Article
- ISSN
- 0168-9002
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A Gaussian version of the iterative proportional fitting procedure (IFP-P) was applied by Speed and Kiiveri to solve the likelihood equations in graphical Gaussian models. The calculation of the maximum likelihood estimates can be seen as the problem to find a Gaussian distribution with prescribed G
## Abstract Iterative least‐squares lineshape fitting of ^1^H‐decoupled ^13^C‐DNMR. spectra is advantageously used for the investigation of symmetrical or asymmetrical intramolecular (two‐structure) exchange processes. The least‐squares procedure adopted allows the following parameters to be either