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Isoxazolium enolates derived from α,β-unsaturated and 1,3-dicarbonyl compounds. The through-space effect of the enolate moiety on the chemical shift of α-protons

✍ Scribed by Gury Zvilichovsky; Vadim Gurvich


Book ID
112131027
Publisher
Journal of Heterocyclic Chemistry
Year
1994
Tongue
English
Weight
223 KB
Volume
31
Category
Article
ISSN
0022-152X

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## Abstract A new cascade pathway viable for Knoevenagel chemistry that involves the coupling between 1,3‐dicarbonyl systems and α,β,γ,δ‐unsaturated aldehydes has been developed. The process comprises the combination of a classic aldol‐type condensation and a rare spontaneous metal‐free cycloisomer