Isotropic chemical shifts and quadrupolar parameters for oxygen-17 using dynamic angle spinning NMR
β Scribed by Mueller, K. T.; Baltisberger, J. H.; Wooten, E. W.; Pines, A.
- Book ID
- 120238870
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 561 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0022-3654
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## Abstract A simple procedure is presented for the determination of the asymmetry parameter of the electric field gradient, the quadrupole coupling constant, the secondβorder quadrupolar shift and the isotropic chemical shift of quadrupolar nuclei with halfβinteger spin directly from the experimen
The 17 O chemical shifts of simple aliphatic ethers were studied, and the additivity substituent increments for carbon atoms in the alkyl groups were determined. The additivity parameters were used to establish a linear correlation with experimental data for a series of aliphatic ethers, alcohols, v