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Isotopic substitution as a symmetry operation in molecular vibrational spectroscopy

✍ Scribed by C.E. Wulfman; R.D. Levine

Book ID: 103025185
Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 355 KB
Volume: 104
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85294-x

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✦ Synopsis

The mass dependence of the eigenvalues of anharmonic oscillators can be discussed by requiring that the potential be invariant under isotopic substitution. The generators of the required symmetry group are explicitly evaluated for the h ¶orse potential.

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