Isotopic shifts of the unit cell constants of the α and β tri-hydrides of uranium: UH3, UD3, UT3

[1,2]-hydride shifts in the reaction of

[1,2]-hydride shifts in the reaction of methyl 5,6-0-cyclohexylidene-3-0-mesyl-α-and β-d-allofuranoside with methylmagnesium iodide

✍ Masajiro Kawana; Sakae Emoto 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 221 KB

Despite the extensive amount of research on nonenzymatic [1,2]-hydride shifts.2 there have been particularly few reports on similar transfers related to carbohydrates.3 We wish to report here the novel example of the stereoselective [1,2]-hydride shifts which occured in the reactions of methyl 3-0-m