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ISOTOPIC PERTURBATION OF RESONANCE—A TERM OF CONTROVERSY

✍ Scribed by Harmut H. Balzer; Stefan Berger

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
91 KB
Volume
10
Category
Article
ISSN
0894-3230

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✦ Synopsis

The term 'isotopic perturbation of resonance' is critically reviewed. With the help of new data obtained from deuteriumlabelled 1,3-dimethyl-and 1,3-di-tert-butylcyclopentenyl cations, it is shown that all observed deuterium isotope effects in these systems are purely intrinsic. The term 'isotopic perturbation of resonance' should no longer be used in the literature.

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