Isotopic fractionation factors of intermolecular hydrogen bonds in water
โ Scribed by Sharon A. Hibdon; Charolette A. Coleman; Jiabing Wang; Christopher J. Murray
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 718 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0045-2068
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๐ SIMILAR VOLUMES
The hydrogen isotopic fractionation factor between brucite and water has been determined in the temperature range of 100~ ~ C. Brucite is always depleted in deuterium relative to the coexisting water, and the degree of depletion becomes larger with decreasing temperature. The fractionation factor ch
The U b b e 1 o h d e effect, i.e. the expansion, or contraction, of the hydrogen bonds in crystals when deuterium is substituted to hydrogen, has not yet been well understood. Suggested interpretations based on a one-dimensional model, including possible resonance or anharmonicity effects seem over