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Isotopic effect in the process of chromium(V) complex formation in the course of ethylene glycol oxidation by dichromate

โœ Scribed by M. Mitewa; P.R. Bontchev; K. Kabassanov; A. Malinovski

Publisher
Elsevier Science
Year
1975
Weight
199 KB
Volume
11
Category
Article
ISSN
0020-1650

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Rates of oxidation of XCOO-(X = H, D) by Brz in acid aqueous media were measured between 274 and 332 K. The derived Arrhenius parameters for both reactions log k ~( M -l S-') = (11.81 f 0.10) -(14.33 f 0.13)/0 log ~D ( M -' S-') = (13.77 f 0.13) -(17.62 f 0.04)/0 where 0 = 4.575T X kcal/mol, with (