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Isotopic 18O exchange between solvent water and aquo molybdenum ions

✍ Scribed by Garry D. Hinch; Donald E. Wycoff; R.Kent Murmann

Book ID
108428993
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
880 KB
Volume
5
Category
Article
ISSN
0277-5387

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The rate of oxygen exchange between truns-[Re(py),02]+ and solvent water in py-pyH' buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25"C, and [pyl = 0.10 M. The observed rate constant for ex