Isotope Specific Kinetics of Hydroxyl Radical (OH) with Water (H 2 O): Testing Models of Reactivity and Atmospheric Fractionation

Cage effect and inverse temperature depe

Cage effect and inverse temperature dependence of the kinetic isotope effect in the c-C6H12/c-C6D12 reaction with OH radicals in fenton and HOONOH2O systems

✍ Elisey S. Rudakov; Vladimir L. Lobachev; Larisa K. Volkova 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB 👁 2 views

## Abstract Recently, we have discovered the unusual inverse temperature dependence of the kinetic isotope effect (KIE) for the OH + __c__‐C~6~H~12~/__c__‐C~6~D~12~ reaction in water. Temperature increase causes a KIE increase; this is valid for both the Fenton system (I) and the HOONOH~2~O system