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Isotope Exchange Rates. I. The Homogeneous Reaction between Deuterium and Ammonia

โœ Scribed by Lifshitz, Assa; Lifshitz, Chava; Bauer, S. H.


Book ID
126083309
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
895 KB
Volume
87
Category
Article
ISSN
0002-7863

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The isotope exchange reaction between hydrogen and deuterium was studied in incident and reflected shock waves over the temperature range 120%1800 K by vacuum ultraviolet absorption spectroscopy. The observed exchange reaction ensued after long induction periods at rates that proved to account for t

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The rate of CHI disappearance in a shock-heated CHI: Dz: Ar = 9.70: 9.86: 80.44 mixture was monitored by coincidence absorption of the 2948 cm-I He-Ne laser line over the shockfront temperature range of 1900-2300K. Comparison with CHr pyrolysis results by means of computer simulations suggested that