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Isotope effects in the production of H*(n = 4) and D*(n = 4) in e-HD collisions

✍ Scribed by Keiji Nakashima; Hirofumi Kawazumi; Teiichiro Ogawa


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
637 KB
Volume
96
Category
Article
ISSN
0301-0104

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The lack of leaving-atom isotope effects
✍ W.H. Breckenridge; Jiang-Hua Wang πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 587 KB

Simple "half-collision" classical trajectories on model potential surfaces show that the lack of leaving-atom isotope effects on initial rotational state distributions P(N) in reactions of the type M\*+H2 (HD) -+MH( v, N) +H (D) would result from decomposition of H-M-H( D) intermediates on anisotrop