## Abstract The ^34^S isotope effect on the chemical shift of P^III^ nuclei in P(SR)~3~ esters [R = Et, (C~12~H~25~)~n~, Ph] is close to 20.6 ppb per P^III^ο£Ώ^34^S bond, i.e. 3β4 times larger than for thiolo sulphur atoms in S = P(SR)~3~ or O = P(SR)~3~. A similar behaviour is noted for the P(ο£ΏSο£Ώ)~3
β¦ LIBER β¦
Isotope effects in 31P NMR of phosphine
β Scribed by A Keith Jameson; Cynthia J Jameson
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 190 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0022-2364
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