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Isotope Effects, Dynamics, and the Mechanism of Solvolysis of Aryldiazonium Cations in Water

โœ Scribed by Ussing, Bryson R.; Singleton, Daniel A.

Book ID
127261606
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
226 KB
Volume
127
Category
Article
ISSN
0002-7863

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Femtosecond photoionization studies in neat protio and deuterio water at room temperature have been performed. The rate of appearance of the solvated electron is slower in D,O than in H,O, consistent with the predictions of continuum theories. The observed geminate recombination dynamics of the cati