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Isotope effects and hyperconjugation

✍ Scribed by Edward S. Lewis


Publisher
Elsevier Science
Year
1959
Tongue
French
Weight
428 KB
Volume
5
Category
Article
ISSN
0040-4020

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We have found that the specific rate of ␣-sulfonyl carbanion formation in a ␀-substituted sulfone shows a sizable dependence on the H C ␣ C ␀ X torsion angle. Defining k N = (k exch ) X /(k exch ) model (where the model has X = H or an alkyl group) we observed for a collection of ␀-alkoxy sulfones (