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Isothiourea-Catalysed Asymmetric C-Acylation of Silyl Ketene Acetals

โœ Scribed by Philip A. Woods; Louis C. Morrill; Dr. Ryan A. Bragg; Dr. Andrew D. Smith


Book ID
102797151
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
502 KB
Volume
17
Category
Article
ISSN
0947-6539

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Asymmetric cyclopropanation of ketene si
โœ Akiharu Satake; Hitomi Kadohama; Hiroyuki Koshino; Tadashi Nakata ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 239 KB

The fwst asymmetric cyclopropanation of ketene silyl acetal with allylic acetate was achieved. New chiral oxazolidinylpyrazole ligands and their TlLallylpalladium complexes were synthesized. Reaction of cinnamyl acetate with ketene silyl acetal of ethyl isobutylate in the presence of a palladium com