Isotacticity effect on crystallization and melting in polypropylene fractions: 1. Crystalline structures and thermodynamic property changes
β Scribed by Stephen Z.D. Cheng; James J. Janimak; Anqiu Zhang; Eric T. Hsieh
- Book ID
- 107846446
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 814 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0032-3861
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Effects of annealing and atactic fraction on structural properties of isotactic polypropylene were investigated using various methods which included X-ray, NMR and DSC. Annealing at elevated temperatures results in considerable increases in crystallinity, ~m, crystal thickness, lc, heat of fusion, A
## Abstract Melt history, pressure, and crystallization temperature are three variables that may be used to vary spherulite size in polymer systems. In this study, bulk polypropylene samples were given various melt treatments and then isothermally crystallized under constant pressure. Spherulite si