Isotactic Polypropylene-Based Stereoregular Diblock Copolymers: Syntheses and Self-Assembly
✍ Scribed by Kuo, Jing-Chung; Lin, Wen-Fu; Yu, Chia-Hue; Tsai, Jing-Cherng; Wang, Tzu-Chung; Chung, Tsai-Ming; Ho, Rong-Ming
- Book ID
- 126058104
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 687 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0024-9297
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## Abstract **Summary:** Amphiphilic diblock copolymers consisting of a hydrophilic block, poly(acrylic acid), and a hydrophobic block, polystyrene, were synthesized by direct nitroxide‐mediated polymerization using the PS block as a macro‐initiator for the first time. Several techniques were used
## Abstract A series of polyacrylonitrile‐__block__‐polystyrene (PAN‐__b__‐PS) and polyacrylonitrile‐__block__‐poly(methyl methacrylate) (PAN‐__b__‐PMMA) diblock copolymers with PAN volume fraction up to 20% self‐assembles in nonpolar selective solvents to form cylindrical micelles with a PAN core,